Product ID:R6 K 32 CYCLOHEXANONE
MSDS Date:11/01/1995
FSC:8010
NIIN:00F049781
MSDS Number: BZWMZ

SHERWIN-WILLIAMS CO/MARTIN SENOUR CO/ROGERS AUTO

101 PROSPECT AVE N W
CLEVELAND, OH 44115-1042
US

Emergency Phone: 216-566-2917/216-566-2902

Info Phone: 216-566-2902/216-566-2917

Cage: 54636

SHERWIN-WILLIAMS CO THE

CLEVELAND, OH 44115-1042 US

Telephone: 800-251-2486/216-566-2242

Cage: 54636

CYCLOHEXANONE, KETOHEXAMETHYLENE

CAS: 108-94-1

RTECS: GW1050000

Fraction By Weight: 100%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:IRRITATION OF EYES/SKIN & RESPIRATORY
SYSTEM, CNS DEPRESSION, DEATH. PROLONGED OVEREXPOSURE TO SOLVENT
MAY CAUSE ADVERSE EFFECTS TO LIVER/URINARY/BLOOD
FORMING/CARDIOVASCULAR & REPRODUCTIVE SYSTEMS. R EPEATED/PROLONGED
OVEREXPOSURE TO SOLVENTS MAY CAUSE PERMANENT BRAIN/NERVOUS SYSTEM
DAMAGE. (SEE SUPP)
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, HEADACHE, DIZZINESS, NAUSEA, LOSS
OF COORDINATION, REDNESS, ITCHING, BURNING, UNCONSCIOUSNESS.

First Aid:INHALATION: REMOVE TO FRESH AIR. SKIN: WASH AFFECTED AREA
THOROUGHLY W/SOAP & WATER. EYES: FLUSH W/LARGE AMOUNTS OF WATER FOR
15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES.

Flash Point:111F
Lower Limits:0.7
Upper Limits:8.1
Extinguishing Media:CO2, DRY CHEMICAL, FOAM
Fire Fighting Procedures:WEAR SCBA & FULL PROTECTIVE EQUIPMENT. WATER
MAY BE USED TO COOL CLOSED CONTAINERS. IF WATER IS USED, FOG
NOZZLES ARE PREFERABLE.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT.

Spill Release Procedures:COVER W/ABSORBENT MATERIAL. VENTILATE AREA &
REMOVE SOURCES OF IGNITION. NEUTRALIZE. AFTER 10 MINS COLLECT IN
OPEN CONTAINERS. COVER LOOSELY. WASH AREA W/SOAP & WATER.
Neutralizing Agent:10% AMMONIUM HYDROXIDE (HOUSEHOLD AMMONIA).

Handling and Storage Precautions:KEEP AWAY FROM IGNITION SOURCES. USE
APPROPRIATE BONDING & GROUNDING PROCEDURES. KEEP AREA VENTILATED.
KEEP CONTAINER CLOSED WHEN NOT IN USE.
Other Precautions:TRANSFER ONLY TO APPROVED CONTAINERS W/COMPLETE &
APPROPRIATE LABEL. DON'T TAKE INTERNALLY/SMOKE. KEEP OUT OF REACH
OF CHILDREN. AVOID BREATHING VAPOR/SPRAY MIST. AVOID CONTACT W/SKIN
& EYES. (SEE SUP P)

Respiratory Protection:NIOSH/MSHA APPROVED POSITIVE PRESSURE AIR
SUPPLIED RESPIRATOR/PROPERLY FITTED VAPOR/PARTICULATE RESPIRATOR
WHERE OVERSPRAY IS PRESENT. NIOSH/MSHA APPROVED DUST/MIST
RESPIRATOR WHEN SANDING/ABRADING DR IED FILM.
Ventilation:LOCAL EXAUST PREFERABLE. GENERAL EXAUST: ACCEPTABLE IF
EXPOSURE LEVEL IS MAINTAINED BELOW APPLICABLE EXPOSURE LIMITS.
Protective Gloves:RECOMMENDED.
Eye Protection:SAFETY GOGGLES W/UNPERFORATED SIDESHIELD
Other Protective Equipment:BARRIER CREAM ON EXPOSED SKIN.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
HEALTH HAZARD CONT'D: MAY CAUSE ALLERGIC RESPIRATORY &/SKIN REACTION IN
SUSCEPTIBLE PEOPLE/SENSITIZATION. OTHER PRECAUTIONS CONT'D:
APPLICATION TO HOT SURFACES REQUIRES SPECIAL PRECAUTIONS.
INTENTIONA L MISUSE BY DELIBERATELY CONCENTRATING & INHALING THE
CONTENTS CAN BE HARMFUL/FATAL.

Boiling Pt:B.P. Text:222-395F
Vapor Density:>1
Spec Gravity:0.8-1.4
VOC Grams/Liter:7.86
Evaporation Rate & Reference:SLOWER THAN ETHER
Percent Volatiles by Volume:13-100

Stability Indicator/Materials to Avoid:YES
WATER, ALCOHOLS, AMINES & OTHER COMPOUNDS WHICH REACT W/ISOCYANATES.
Stability Condition to Avoid:EXTREME HEAT & OTHER IGNITION SOURCES.
Hazardous Decomposition Products:BY FIRE: CO, CO2, OXIDES OF NITROGEN,
POSSIBILITY OF HYDROGEN CYANIDE.

Waste Disposal Methods:INCINERATE IN APPROVED FACILITY. DON'T
INCINERATE CLOSED CONTAINERS. WASTE MUST BE TESTED FOR
IGNITABLILITY TO DETERMINE APPLICABLE EPA HAZARDOUS WASTE NUMBERS.
DISPOSE OF IAW/LOCAL, STATE & FEDERAL R EGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.